Contaminant migration through the permafrost active layer, Mackenzie Delta area, Northwest Territories, Canada

• Published in: Polar Record
• Main Author: Dyke, Larry D.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Cambridge University Press (CUP) 2001
• Subjects: General Earth and Planetary Sciences; Ecology; Geography, Planning and Development; Arctic; Northwest Territories; Canada; Mackenzie Delta; Ice; permafrost; Polar Record; Tundra
• Online Access: http://dx.doi.org/10.1017/s0032247400027248; https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0032247400027248

Abstract Buried pits (sumps), used for the disposal of drilling muds in the Mackenzie Delta area of Arctic Canada, provide an opportunity for assessing the effectiveness of ice-bonded permafrost sediments as a containment for industrial wastes. Potassium chloride (KCI) added to drilling muds as a freezing-point depressant provides a suitable tracer, because it is easily identified and natural concentrations in sediment pore water are typically low (less than 0.02 g l −1 potassium). Muds with KCI concentrations of up to 10% by weight (100 g l −1 ) have been used. In the vicinity of sumps, potassium is found at elevated concentrations of up to several g l −1 in the seasonal thaw layer (active layer) at distances well beyond what would be expected from diffusive transport alone. Within the level alluvial silts of the modern Mackenzie Delta, KCI has moved up to 50 m laterally from sump edges. On surrounding tundra uplands, KCI has migrated several hundred metres downslope within the active layer. Although ice-rich permafrost sediments appear to form an effective barrier against downward movement of solutes, thawing ice lenses and veins within the active layer greatly increase the lateral hydraulic conductivity in this zone during the thaw season. Compared with unfrozen silty sediments, the large pores left by thawed ice fabric in the same sediment after a freeze–thaw cycle have been shown to increase the hydraulic conductivity up to four orders of magnitude. This phenomenon is probably common in thawing, ice-rich sediments and presumably favours accelerated downhill movement of solutes. On level ground, it is anticipated that KCI movement is promoted by fluid densities approaching that of sea water. Laboratory experiments with thawed sand and both unfrozen and thawing Mackenzie Delta silt confirm the existence of density-driven solute movement and the importance of thawing ice fabric in promoting solute movement. The thawed ice fabric of active-layer sediments and the presence of a frost table promote lateral ...