The Distortion of a Water Molecule in Ice
Abstract The experimental evidence for the distortion of a water molecule when it is condensed to form ice is reviewed. The specific distortions considered are the changes in inter-nuclear distances, energy and its derivatives with respect to nuclear motion, and electrical moments and polarizabiliti...
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Language: | English |
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Cambridge University Press (CUP)
1978
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Online Access: | http://dx.doi.org/10.1017/s002214300003327x https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S002214300003327X |
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crcambridgeupr:10.1017/s002214300003327x 2024-03-03T08:45:59+00:00 The Distortion of a Water Molecule in Ice Whalley, E. 1978 http://dx.doi.org/10.1017/s002214300003327x https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S002214300003327X en eng Cambridge University Press (CUP) Journal of Glaciology volume 21, issue 85, page 13-31 ISSN 0022-1430 1727-5652 Earth-Surface Processes journal-article 1978 crcambridgeupr https://doi.org/10.1017/s002214300003327x 2024-02-08T08:36:10Z Abstract The experimental evidence for the distortion of a water molecule when it is condensed to form ice is reviewed. The specific distortions considered are the changes in inter-nuclear distances, energy and its derivatives with respect to nuclear motion, and electrical moments and polarizabilities and their response to nuclear motion. Some of the properties of ice can be expanded as Fourier or Taylor series in the ratio r/R of the O–H to the O—O distances, and these expansions are used to relate various properties of the intermolecular potential energy, of the electrical dipole moments, and of the polarizability. For example, the amplitude of the orientation polarization can be related to the infrared intensity of the fundamental and first overtone infrared bands. Article in Journal/Newspaper Journal of Glaciology Cambridge University Press Journal of Glaciology 21 85 13 31 |
institution |
Open Polar |
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Cambridge University Press |
op_collection_id |
crcambridgeupr |
language |
English |
topic |
Earth-Surface Processes |
spellingShingle |
Earth-Surface Processes Whalley, E. The Distortion of a Water Molecule in Ice |
topic_facet |
Earth-Surface Processes |
description |
Abstract The experimental evidence for the distortion of a water molecule when it is condensed to form ice is reviewed. The specific distortions considered are the changes in inter-nuclear distances, energy and its derivatives with respect to nuclear motion, and electrical moments and polarizabilities and their response to nuclear motion. Some of the properties of ice can be expanded as Fourier or Taylor series in the ratio r/R of the O–H to the O—O distances, and these expansions are used to relate various properties of the intermolecular potential energy, of the electrical dipole moments, and of the polarizability. For example, the amplitude of the orientation polarization can be related to the infrared intensity of the fundamental and first overtone infrared bands. |
format |
Article in Journal/Newspaper |
author |
Whalley, E. |
author_facet |
Whalley, E. |
author_sort |
Whalley, E. |
title |
The Distortion of a Water Molecule in Ice |
title_short |
The Distortion of a Water Molecule in Ice |
title_full |
The Distortion of a Water Molecule in Ice |
title_fullStr |
The Distortion of a Water Molecule in Ice |
title_full_unstemmed |
The Distortion of a Water Molecule in Ice |
title_sort |
distortion of a water molecule in ice |
publisher |
Cambridge University Press (CUP) |
publishDate |
1978 |
url |
http://dx.doi.org/10.1017/s002214300003327x https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S002214300003327X |
genre |
Journal of Glaciology |
genre_facet |
Journal of Glaciology |
op_source |
Journal of Glaciology volume 21, issue 85, page 13-31 ISSN 0022-1430 1727-5652 |
op_doi |
https://doi.org/10.1017/s002214300003327x |
container_title |
Journal of Glaciology |
container_volume |
21 |
container_issue |
85 |
container_start_page |
13 |
op_container_end_page |
31 |
_version_ |
1792501758759534592 |