Challenges in Radiocarbon Dating Organic Carbon in Opal-Rich Marine Sediments
We explored the reliability of radiocarbon ages obtained on organic carbon phases in opal-rich Southern Ocean sediments. Paired biogenic carbonate and total organic carbon (TOC) 14 C analyses for three Southern Ocean cores showed that the TOC ages were systematically younger than the carbonate ages....
| Published in: | Radiocarbon |
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| Main Authors: | , , , , , |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Cambridge University Press (CUP)
2002
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| Subjects: | |
| Online Access: | https://doi.org/10.1017/s0033822200064729 https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0033822200064729 |
| Summary: | We explored the reliability of radiocarbon ages obtained on organic carbon phases in opal-rich Southern Ocean sediments. Paired biogenic carbonate and total organic carbon (TOC) 14 C analyses for three Southern Ocean cores showed that the TOC ages were systematically younger than the carbonate ages. Carbonate ages were consistent with oxygen isotopic and bio-stratigraphy, indicating error in TOC ages that could be explained by 5–24% of modern carbon contamination of TOC samples. Two possible sources of contamination are: 1) adsorption of atmospheric CO 2 or volatile organic compounds to reactive opal surface sites, and 2) fixation of atmospheric CO 2 by chemosynthetic bacteria during core storage. In an effort to reduce the modern carbon contamination, diatoms were separated from sediments, purified, and pre-oxidized by concentrated nitric and perchloric acids to permit dating of opal-intrinsic organic carbon (~0.1–0.3% by weight). 14 C ages of chemically pre-oxidized opal showed a significant amount of modern carbon contamination, from 11 to 32%, indicating adsorption from the atmosphere of modern carbon onto opal surfaces that were previously cleaned by acid oxidation. Several experiments designed to eliminate the modern C contamination were attempted, but so far we have not been able to obtain a radiocarbon age on 14 C-dead Southern Ocean opal-rich sediments, either bulk TOC or purified diatom opal samples, as old as our procedural blank. |
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