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100 pm level 4 ° c 5 buffer Biochemistry Biophysics Biotechnology Chemical Sciences not elsewhere classified Computational Biology Inorganic Chemistry Medicine Molecular Biology Plant Biology Space Science amino acid biosignatures amino acid labeling analyte labeling develop methods efficiency separations enable selective analysis extraterrestrial samples fluorescence labeling hydrolysis time initial labeling time initial pb concentration labeling efficiency labeling kinetics optimized conditions optimized labeling pacific blue pb concentration