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Dissolved organic matter Mediterranean Sea marine environment DOM Biological carbon pump Cape Vert frontal zone Cell size Characteristic molecular indices for water masses Chemical extraction DOM molecular fingerprint DON DON exported to overturning oceanic circulation DON production Dark ocean Deep sea Eastern subpolar North Atlantic European ocean margin FT-ICR MS measurements Functional traits Mass spectroscopy Mesopelagic zone NW Iberian margin Northeast atlantic ocean Nutrients Ocean circulation Optimum multiparameter water mass analysis Particulate organic carbon Phytoplankton Prokaryotes Sea surface temperature